The term :expansion chamber " in the exhaust world usually refers to the part of a 2 stroke exhaust system that creates a negative pulse to pull out the exhaust and then create a positive pulse to stop the flow of intake gases from following the exhaust gases out of the cylinder. What your talking about are the collector boxes on the ends of the header pipes that collect the exhaust and reroute through a single pipe to the mufflers. The collectors act more like resonators in a 4 stroke exhaust system, merging the pulses and if properly designed help reduce the peaks of the pulses which will help cancel out the noise at certain frequencies.
The inline 6 cylinder engine is the perfect engine for a 6 into 2 exhaust system and when designed properly can add some significant horsepower. Also, a 6 into 2 into 1 will add more than a 6 into 2 but the work involved is also significant. The only major saving is the weight of the system and the sound difference .
A good read if your into it is this book.
scientific design of intake and exhaust systems by Phillip H Smith.
I have kept a copy of this in the workshop for YEARS. At some point, God willing, I will do a system for the bike. House reno are stalling out my "shop time" right now. 1600 ft of hardwood going down, new kitchen to install in 2 weeks then 2 bathrooms to gut and rebuild and convert a 2nd bedroom into a walk in closet. Funny how life gets in the way but you do what you have to to survive.